منابع مشابه
Chemical bonding in hypervalent molecules: is the octet rule relevant?
The bonding in a large number of hypervalent molecules of P, As, S, Se, Te, Cl, and Br with the ligands F, Cl, O, CH(3), and CH(2) has been studied using the topological analysis of the electron localization function ELF. This function partitions the electron density of a molecule into core and valence basins and further classifies valence basins according to the number of core basins with whic...
متن کاملIsostrychnine synthesis mediated by hypervalent iodine reagent.
Althought there are several reported synthetic routes to strychnine, one of the most widely recognized alkaloids, we report an unexplored route with an oxidative dearomatizing process mediated by hypervalent iodine as the key step. The new syntheses of isostrychnine and strychnine have been achieved from an readily available phenol in nine and ten steps. In addition to the key step, these synth...
متن کاملAsymmetric Synthesis with Hypervalent Iodine Reagents.
This chapter describes recent developments in stereoselective synthesis using hypervalent iodine reagents.
متن کاملPseudopotential Scf-mo Studies of Hypervalent Compounds
The (ab initio) effective potential method developed previously has been applied to several molecules in order to establish a basis set and effective potential for iodine and to examine aspects of the potential surfaces of hypervalent compounds of iodine. Implied lone-pair stereochemical activity is found to agree well with experiment. Results for the structures and force constants closely rese...
متن کاملElectrophilic alkynylation of ketones using hypervalent iodine.
A new method for the electrophilic α-alkynylation of ketones was developed using hypervalent iodine under mild and metal-free conditions. Carbonyl compounds containing an α-acetylene group were obtained in good to excellent yields for several ketones using 1-[(trimethylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one (TMS-EBX) as an alkynylation agent in the presence of t-BuOK and TBAF in THF as solven...
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ژورنال
عنوان ژورنال: RADIOISOTOPES
سال: 2000
ISSN: 0033-8303,1884-4111
DOI: 10.3769/radioisotopes.49.385